Organic compounds are often written as structural formulae, with lines representing bonds.
Structural formulae may be expanded, condensed, or skeletal:
- Expanded form has each hydrogen atom drawn individually coming off the carbons.
- Condensed form has the hydrogens for each carbon written directly next to it.
- Skeletal form means not writing the letters for carbon or hydrogen at all - the chains are drawn as straight lines with corners, where each corner represents a carbon and all its necessary hydrogens.
The number of bonds on each element follows specific rules:
- Carbon atoms must have exactly 4 bonds each
- Hydrogen atoms must have exactly 1 bond each
- Neutral oxygen atoms must have exactly 2 bonds each, and oxygen atoms with a 1- charge must have exactly 1 bond each
- Neutral nitrogen atoms must have exactly 3 bonds each, and nitrogen atoms with a 1+ charge must have exactly 4 bonds each
Number of carbons in main chains or side chains is determined by these prefixes:
- meth = 1 carbon
- eth = 2 carbons
- prop = 3 carbons
- but = 4 carbons
- pent = 5 carbons
- hex = 6 carbons
- hept = 7 carbons
- oct = 8 carbons
Functional group positions are indicated by numbers, with each number representing a carbon along the main chain (or a bond on the main chain, for alkene and alkyne groups.
A table of functional group formulae and names is attached.
If there are multiple of the same functional group in the compound, this will be indicated by a prefix:
- di = 2 of the same group
- tri = 3 of the same group
- tetra = 4 of the same group
The melting and boiling point of a compound depends on the strength of secondary forces:
- The strength of dispersion forces (longer chains lead to higher melting/boiling points)
- The presence of polar groups (more polar groups leads to higher melting/boiling points)
The solubility of a compound in another depends on how similar their secondary forces are. Compounds with a shorter nonpolar hydrocarbon chain and more polar groups will tend to dissolve better in water, because it is highly polar.
Some of the common reactions between organic compounds include:
- combustion (burning in the presence of oxygen gas) to produce carbon dioxide and water
- addition (combining a small molecule onto a larger molecule) for example addition of bromine to an unsaturated compound
- elimination (producing a small molecule from a larger molecule) for example condensation of water in esterification
- oxidation, for example of a primary alcohol to an aldehyde, of a secondary alcohol to a ketone, or of an aldehyde to a carboxylic acid
- reaction of an aldehyde with Tollen's reagent to produce a silver mirror
- hydrolysis (reaction with water)
Some organic compounds are quite unreactive, for example:
- Tertiary alcohols are not oxidised
- Benzene is a reasonably unreactive group
Organic practice programs: reactions | products | polymers/monomers
Isomers are compounds that have the same molecular formula (number of each element) but different shape. Homologous series include compounds with the same general formula (the molecular formula follows a certain pattern).