3.7 Esters
Naming and drawing esters
Carboxylic acids undergo condensation reactions with alcohols to form esters.
- Identify, name systematically, and draw structural formulae of methyl and ethyl esters of acids containing up to eight carbon atoms in the main chain, with side chains limited to a maximum of two carbon atoms.
- Draw the structural formula of the ester that could be produced by the condensation reaction between a carboxylic acid and an alcohol, given their structural formulae or vice versa.
- Draw the structural formula of a polyester, given the structural formula(e) of the monomer(s) or vice versa.
Infographic: Flavour/scent esters
Reference sheet: Functional groups
Practice programs: Naming | Drawing (choose Ester)
Tool: Draw from name
Preparation of esters
Condensation reactions are slow at 25°C.
- Explain the use of heating under reflux, and the use of a trace of concentrated sulfuric acid in the laboratory preparation of esters.
Video: Reflux demonstration
Hydrolysis of esters
Esters may be hydrolysed under acidic or alkaline conditions.
- Identify the products of acidic or alkaline hydrolysis of an ester or polyester, given the appropriate structural formula.
Video: Flippin' Science
Practice: Organic Products (choose Esterification/hydrolysis) | Polymer